The importance of solvent reorganisation in the effect of an ionic liquid on a unimolecular substitution process
2008; Royal Society of Chemistry; Issue: 30 Linguagem: Inglês
10.1039/b805255g
ISSN1364-548X
AutoresHon Man Yau, Susan A. Barnes, James M. Hook, Tristan G. A. Youngs, Anna K. Croft, Jason B. Harper,
Tópico(s)Chemistry and Chemical Engineering
ResumoTemperature dependent rate studies demonstrate an enthalpic benefit and an entropic cost associated with the change in the rate of a unimolecular substitution process on addition of a high proportion of an ionic liquid, the latter effect being supported by molecular dynamics simulations.
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