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Simple NUF 3 and PUF 3 Molecules with Triple Bonds to Uranium

2008; Wiley; Volume: 47; Issue: 29 Linguagem: Inglês

10.1002/anie.200801120

1521-3773

Lester Andrews, Xuefeng Wang, Roland Lindh, Björn O. Roos, Colin J. Marsden,

Inorganic Fluorides and Related Compounds

UN-beatable? Laser-ablated uranium atoms activate NF3 and PF3 to form the NUF3 and PUF3 molecules containing novel terminal nitride and phosphide functional groups. These molecules are identified from matrix infrared spectra and theoretical methods. The NUF3 molecule contains the strongest triple bond to uranium in a ternary compound. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z801120_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.