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The electric dipole moment function of HF

1988; IOP Publishing; Volume: 21; Issue: 9 Linguagem: Inglês

10.1088/0953-4075/21/9/023

1361-6455

J. F. Ogilvie,

Advanced Chemical Physics Studies

Based on experimental data with improved accuracy, a new determination of the electric dipole moment function of the molecule HF in the X 1 Sigma + electronic state has been made. The new results are presented in the forms both of a power series, valid within the range of internuclear separation 0.69( R/10-10m(1.45, and of a rational function at least qualitatively valid at all larger internuclear distances. The rotational dependence of expectation values of the electric dipole moment operator is also investigated.