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Artigo Revisado por pares
BIBTEX RIS

The reaction of benzene with diethylamine in the presence of an iridium(I)/mercury(II) based system: a model route for the direct amination of aromatic hydrocarbons

1995; Elsevier BV; Volume: 494; Issue: 1-2 Linguagem: Inglês

10.1016/0022-328x(94)05391-n

ISSN

1872-8561

Autores

Pietro Diversi, Luca Ermini, Giovanni Ingrosso, Antonio Lucherini, Calogero Pinzino, Laura Sagramora,

Tópico(s)

Carbon dioxide utilization in catalysis

Resumo

N,N-Diethylaniline is formed under mild conditions either by the direct amination of benzene with diethylamine in the presence of [Ir(η5-C5Me5)(CO)2] 1 and HgSO4, or by reacting (C6H5)2Hg or C6H5HgCl/Ag2SO4 with diethylamine in the presence of 1. A preliminary investigation about the chemistry underlying these reactions is also reported.

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