Phase equilibria of AgI-AgBr system
1984; Elsevier BV; Volume: 14; Issue: 2 Linguagem: Inglês
10.1016/0167-2738(84)90083-3
ISSN1872-7689
AutoresH. Takahashi, S. Tamaki, S. Harada,
Tópico(s)Chemical Thermodynamics and Molecular Structure
ResumoThe phase diagram and the heat of transition of AgI-AgBr system have been determined by using the differential scanning calorimetry (DSC) with the help of X-ray diffraction patterns. It has been verified that the miscibility gap between β-AgI-type solid solution and AgBr-type one depends on the thermal history of the sample. From the thermodynamic point of view, it is likely that the variation of transition temperature with composition suggests the change of correlation among silver ions in superionic conducting phase.
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