Synthesis, Structure, and Reactivity of [Cp 2 Ti(HBcat)(PMe 3 )]: A Monoborane σ Complex
1997; Wiley; Volume: 36; Issue: 13-14 Linguagem: Inglês
10.1002/anie.199715101
ISSN1521-3773
AutoresClare N. Muhoro, Johan F. Hartwig,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoA significant BH interaction is detected in the TiII compound 1, the first monoborane σ complex. This complex undergoes ligand substitution with CO to form 2 and transfers catecholborane to diphenylacetylene to form 3.
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