Artigo Revisado por pares

Synthesis, Structure, and Reactivity of [Cp 2 Ti(HBcat)(PMe 3 )]: A Monoborane σ Complex

1997; Wiley; Volume: 36; Issue: 13-14 Linguagem: Inglês

10.1002/anie.199715101

ISSN

1521-3773

Autores

Clare N. Muhoro, Johan F. Hartwig,

Tópico(s)

Organometallic Complex Synthesis and Catalysis

Resumo

A significant BH interaction is detected in the TiII compound 1, the first monoborane σ complex. This complex undergoes ligand substitution with CO to form 2 and transfers catecholborane to diphenylacetylene to form 3.

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