Generalized van der waals theory: a classical perspective
1987; Elsevier BV; Volume: 37; Linguagem: Inglês
10.1016/0378-3812(87)80042-0
ISSN1879-0224
AutoresMichael M. Abbott, John M. Prausnitz,
Tópico(s)Advanced Thermodynamics and Statistical Mechanics
ResumoGeneralized van der Waals theory is a powerful instrument for deriving and applying equations of state. Normally, the basis for the theory is a particular factorization of the canonical-ensemble partition function. We present here an alternative formulation--clean and classical--which allows one to postpone molecular considerations until they are needed.
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