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Nitrated Benzyne Derivatives of La@C 82 : Addition of NO 2 and Its Positional Directing Effect on the Subsequent Addition of Benzynes

2009; Wiley; Volume: 49; Issue: 3 Linguagem: Inglês

10.1002/anie.200905024

1521-3773

Xing Lü, Hidefumi Nikawa, Takahiro Tsuchiya, Takeshi Akasaka, M. Toki, Hiroshi Sawa, Naomi Mizorogi, Shigeru Nagase,

Boron and Carbon Nanomaterials Research

Dragon Ball La: The unprecedented addition of NO2 and two benzene moieties to metallofullerene La§C82 is described. The X-ray structure (see picture, right) shows an NO2 group that is singly bound to a cage carbon that has a high degree of radical character, and two benzene moieties that are linked to highly pyramidalized cage carbon atoms through [5,6]-bond junctions. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.