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On the Synthesis and Enantiomeric Purity of ( S )-4-Acetyl-2,2-Dimethyl-1,3-Dioxolane

1986; Taylor & Francis; Volume: 16; Issue: 12 Linguagem: Inglês

10.1080/00397918608056404

1532-2432

David Tanner, Peter Somfai,

Asymmetric Synthesis and Catalysis

Abstract The title ketone has been synthesised in 96% e.e. from the corresponding methyl ester and MeLi. The [α]D value for the product was considerably higher than values previously reported for the enantiomer.