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BIBTEX RIS

Direct Proof for OMn v (salen) Complexes

1997; Wiley; Volume: 36; Issue: 16 Linguagem: Inglês

10.1002/anie.199717181

ISSN

1521-3773

Autores

Derek Feichtinger, Dietmar A. Plattner,

Tópico(s)

Porphyrin and Phthalocyanine Chemistry

Resumo

Electrospray mass spectroscopy has finally provided proof for the formation of oxomanganese(v) complexes such as 1 under the conditions of the Kochi-Jacobson-Katsuki epoxidation. Collision of 1 with olefins or sulfides in the gas phase regenerates the initial (salen)MNIII complexes by transfer of the oxygen atom.

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