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Thermogravimetric studies of decomposition kinetics of six different IAC Hevea rubber clones using Flynn–Wall–Ozawa approach

2006; Taylor & Francis; Volume: 35; Issue: 1 Linguagem: Inglês

10.1179/174328906x79932

1743-2898

R. M. B. Moreno, Eliton S. Medeiros, Fábio Cop Ferreira, Neri Alves, P.S. Gonçalves, L. H. C. Mattoso,

Polymer crystallization and properties

The thermal degradation behaviour of rubber from six new Hevea brasiliensis clones (IAC 40, 56, 300, 301, 302 and 303) from São Paulo State, Brazil was studied by thermogravimetry using the Flynn–Wall–Ozawa approach to assess the kinetic parameters (reaction order, activation energy and pre-exponential factor) of the decomposition process. This study indicated that the thermal behaviour is a complex multiple step process, which depends on the type of rubber Hevea clones studied. The rubber from these clones can be classified, following the order of decreasing thermal stability, as IAC 303 > 302 > 56 > 40 > 300 > 301.