Voltar
Artigo Acesso aberto Revisado por pares
BIBTEX RIS

Microwave-Assisted Cyanation of an Aryl Bromide Directly on a Metal−Organic Framework

2011; American Chemical Society; Volume: 50; Issue: 3 Linguagem: Inglês

10.1021/ic102436b

ISSN

1520-510X

Autores

Min Kim, Sergio J. Garibay, Seth M. Cohen,

Tópico(s)

Chemical Synthesis and Reactions

Resumo

A microwave-assisted postsynthetic modification (PSM) reaction on a metal-organic framework (MOF) has been realized. Cyanation of the Zr(4+)-based UiO-66-Br was achieved with CuCN and microwave irradiation to produce UiO-66-CN. This protocol represents a notable example of PSM on an aryl halide MOF producing a cyano-functionalized MOF.

Referência(s)