Studies of Ziegler-type catalysts for the polymerization of ethylene and propylene—III the polymerization of propylene with TiCl4-MgCl2-based catalysts
1979; Elsevier BV; Volume: 15; Issue: 7 Linguagem: Inglês
10.1016/0014-3057(79)90086-7
ISSN1873-1945
AutoresE.W. Duck, D. Grant, E. Kronfli,
Tópico(s)Carbon dioxide utilization in catalysis
ResumoAbstract It has been confirmed that a reaction product of TiCl 4 and MgCl 2 is an extremely active catalyst for the polymerization of propylene. This catalyst is markedly different from the usual Ziegler-Natta TiCl 3 catalyst in the dependence of its reactivity on additions of aluminium alkyl co-catalyst and Lewis base.
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