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The High-Resolution Spectrum of the ν1 Band and Ground State Rotational Constants of HOCl

1994; Elsevier BV; Volume: 164; Issue: 2 Linguagem: Inglês

10.1006/jmsp.1994.1102

1096-083X

M-L. Junttila, W. J. Lafferty, James B. Burkholder,

Molecular Spectroscopy and Structure

The experimentally measured high-resolution rovibrational spectra of H16O35Cl, collated from 16 sources, have been analyzed using the Marvel (Measured Active Rotational–Vibrational Energy Levels) procedure. The compilation presented, the most extensive up to now, considers a total of 21 464 transitions, allowing the derivation of 6277 empirical energy levels, extending up to 17 161 cm−1, corresponding to 15 vibrational parent states. Experimental transitions data from three older sources, not published explicitly in the original papers, are presented for the first time; they represent about one half of all the transitions investigated.