cis-trans Isomerization of PtCl2[PeT3]2. Evidence against a consecutive displacement mechanism
1974; Royal Society of Chemistry; Issue: 9 Linguagem: Inglês
10.1039/c3974000353a
ISSN2050-5639
Autores Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoThe complex PtCl[PEt3]3+ does not react with chloride to form cis or trans PtCl2[PEt3]2 and when a different phosphine is used to catalyse the cis–trans isomerization ofPtCl2[PEt3]2, the phosphines do not mix during isomerization; these data contradict the consecutive displacement mechanism.
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