The Dissociation Equilibrium of the Copper(II) Acetate Dimer in Acetic Acid
1990; Oxford University Press; Volume: 63; Issue: 6 Linguagem: Inglês
10.1246/bcsj.63.1819
ISSN1348-0634
AutoresYoichi Kikuchi, Toshio Suzuki, Kiyoshi Sawada,
Tópico(s)Chemical and Physical Properties in Aqueous Solutions
ResumoAbstract The dissociation equilibrium of the copper(II) acetate dimer in acetic acid was studied by means of high-sensitivity spectorophotometry. The dissociation constant of the nonaquated dimer was determined to be Kdis=10−6.2±0.2 at 25 °C. The dissociation was promoted in the presence of water. The formation constant of the monoaquated monomer was estimated to be Kml=3.0.
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