Artigo Revisado por pares

Excess volumes and excess heat capacities of nitromethane+(1-propanol or 2-propanol)

1999; Elsevier BV; Volume: 157; Issue: 1 Linguagem: Inglês

10.1016/s0378-3812(99)00018-7

ISSN

1879-0224

Autores

Claudio A. Cerdeiriña, Clara A. Tovar, Jacobo Troncoso, E. Carballo, Luis Romanı́,

Tópico(s)

Chemical Thermodynamics and Molecular Structure

Resumo

Densities and heat capacities of binary mixtures containing nitromethane+(1-propanol or 2-propanol) were determined at the temperatures (288.15, 293.15, 298.15, and 308.15) K and atmospheric pressure, over the whole composition range. Excess molar volumes and excess molar isobaric heat capacities were calculated from the results thus obtained. The effect of specific interactions on the excess properties, and the dependence on the position of the OH group in the alkanol, are analysed.

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