Voltar
Artigo
BIBTEX RIS

Beiträge zum thermischen Verhalten wasserfreier Phosphate

1992; De Gruyter; Volume: 198; Issue: 1-2 Linguagem: Inglês

10.1524/zkri.1992.198.1-2.41

ISSN

2366-1798

Autores

Robert Glaum, R. Gruehn,

Tópico(s)

Organometallic Compounds Synthesis and Characterization

Resumo

We describe the synthesis and crystallisation by means of chemical vapour transport reactions of TiPO4 and VPO4. TiPO4 (a = 5.2985(5) Å, b = 7.911(1) Å, c = 6.3473(5) Å) and VPO4 (a = 5.2316(5) Å, b = 7.7738(7) Å, c = 6.2847(5) Å) adopt the crystal structure of chromiumvanadate CrVO4 (Cmcm, Z = 4). The results of the refinements of both crystal structures from single crystal data are given. TiPO4 (VPO4): 335 (223) symmetry independent reflections from 1260 (1439) reflections, 22 (22) variables, residuals. R = 0.062 (0.049).

Referência(s)