Model-free analysis of thermoanalytical data-advantages and limitations
2002; Elsevier BV; Volume: 391; Issue: 1-2 Linguagem: Inglês
10.1016/s0040-6031(02)00169-7
ISSN1872-762X
AutoresJ. Opfermann, E. Kaisersberger, H.‐J. Flammersheim,
Tópico(s)Catalysis and Oxidation Reactions
ResumoModel-free kinetic analysis is a powerful tool to estimate the activation energy of processes, investigated by various isothermal or dynamic measurements. On the basis of real measurements and simulations we demonstrate that limitations of application exist. Conditions are listed under which estimated values of activation energy could be incorrect.
Referência(s)