Asymmetric hydrogenation of ketones catalyzed by a ruthenium(ii)-indan–ambox complex
2010; Royal Society of Chemistry; Volume: 46; Issue: 22 Linguagem: Inglês
10.1039/b927028k
ISSN1364-548X
AutoresWei Li, Guohua Hou, Chun‐Jiang Wang, Yutong Jiang, Xumu Zhang,
Tópico(s)Catalysis for Biomass Conversion
Resumo(S,R)-Indan–ambox ligand and its ruthenium(II) complex have been prepared and successfully applied to asymmetric hydrogenation of prochiral simple ketones. A wide range of unfunctionalized ketones are reduced by Ru(II)-indan–ambox catalyst with excellent enantioselectivities (up to 97% ee).
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