New route to (−)-frontalin and (−)-malyngolide via epoxyketone rearrangement
1991; Elsevier BV; Volume: 47; Issue: 34 Linguagem: Inglês
10.1016/s0040-4020(01)96151-4
ISSN1464-5416
AutoresMorio Asaoka, Satoshi Hayashibe, S. SONODA, Hisashi Takei,
Tópico(s)Microbial Natural Products and Biosynthesis
ResumoSynthesis of the title compounds by utilizing BF3·Et2O catalyzed ring contraction of 2,3-epoxycyclohexanones leading to 2-alkyl-2-formylcyclopentanones is described.
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