‘Click’ synthesis of ferrocenyl-, biferrocenyl-, and cobalticenyl-triazolyl-β-cyclodextrins
2010; Elsevier BV; Volume: 51; Issue: 35 Linguagem: Inglês
10.1016/j.tetlet.2010.06.115
ISSN1873-3581
AutoresAbdou K. Diallo, Stéphane Menuel, Éric Monflier, Jaimé Ruiz, Didier Astruc,
Tópico(s)Advanced biosensing and bioanalysis techniques
ResumoCuI-catalyzed Huisgen-type dipolar 'click' reactions between azidomethyl-β-cyclodextrin and ethynylferrocene, ethylnylcobaltocenium hexafluorophosphate, and bis(ethynyl)-biferrocene yield the corresponding metallocenyl-1,2,3-triazolyl-β-cyclodextrins. The monometallocenyl 1,2,3-triazolyl-β-cyclodextrins are soluble in water, unlike the biferrocene derivative.
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