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Facile P–C bond cleavage in the reactions of nitrile oxides with zerovalent triphenylphosphine platinum complexes

1981; Royal Society of Chemistry; Issue: 10 Linguagem: Inglês

10.1039/c39810000446

2050-5639

Wolfgang Beck, Michael Keubler, Erich Leidl, Ulrich Nagel, Mathias Schaal, Sergio Cenini, Paola Del Buttero, Emanuela Licandro, Stefano Maiorana, A. CHIESI VILLA,

Oxidative Organic Chemistry Reactions

Stable nitrile oxides react with Pt(PPh3)2L (L = PPh3,C2H4) to give 1 : 1 products; X-ray studies show that the nitrile oxide is deoxygenated by triphenyl-phosphine and that a phenyl group migrates to the platinum atom to give the complexes [Pt(Ph)(OPPh2)(RCN)(PPh3)].