Isomeric Forms of Divalent Heavier Group 14 Element Hydrides: Characterization of Ar‘(H)GeGe(H)Ar‘ and Ar‘(H) 2 GeGeAr‘·PMe 3 (Ar‘ = C 6 H 3 -2,6-Dipp 2 ; Dipp = C 6 H 3 -2,6-Pr i 2 )

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Isomeric Forms of Divalent Heavier Group 14 Element Hydrides: Characterization of Ar‘(H)GeGe(H)Ar‘ and Ar‘(H) 2 GeGeAr‘·PMe 3 (Ar‘ = C 6 H 3 -2,6-Dipp 2 ; Dipp = C 6 H 3 -2,6-Pr i 2 )

2003; American Chemical Society; Volume: 125; Issue: 11 Linguagem: Inglês

10.1021/ja029772g

ISSN

1943-2984

Autores

Emma Richards, A.D. Phillips, Marilyn M. Olmstead, Philip P. Power,

Tópico(s)

Coordination Chemistry and Organometallics

Resumo

The reduction of Ar'GeCl (Ar' = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) with LiBH(Bus)3 affords the first heavier group 14 element dimetallene hydride Ar'(H)GeGe(H)Ar' which, upon further reaction with PMe3, yields the base-stabilized isomeric form Ar'(H)2GeGeAr'·PMe3.

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Isomeric Forms of Divalent Heavier Group 14 Element Hydrides: Characterization of Ar‘(H)GeGe(H)Ar‘ and Ar‘(H) 2 GeGeAr‘·PMe 3 (Ar‘ = C 6 H 3 -2,6-Dipp 2 ; Dipp = C 6 H 3 -2,6-Pr i 2 )