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BIBTEX RIS

Synthesis of Tunable Bisphosphine Ligands and Their Application in Asymmetric Hydrogenation of Quinolines

2008; American Chemical Society; Volume: 73; Issue: 14 Linguagem: Inglês

10.1021/jo800779r

ISSN

1520-6904

Autores

Xiaobing Wang, Yong‐Gui Zhou,

Tópico(s)

Carbon dioxide utilization in catalysis

Resumo

A series of tunable axial chiral bisphosphine ligands have been synthesized from (S)-MeO-Biphep. The Ir complex of the MeO-PEG-supported ligand (S)-4k has been successfully applied in asymmetric hydrogenation of quinolines with up to 92% ee. The catalyst system is air-stable and recyclable.

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