Artigo
Synthesis of vinyl epoxides via a three-component coupling
1998; Issue: 23 Linguagem: Inglês
10.1039/a807805j
ISSN2050-8255
AutoresMartin W. Rowbottom, Neil Mathews, Timothy Gallagher,
Tópico(s)Synthesis and Catalytic Reactions
ResumoThe butadienylsulfonium species 1 undergoes stepwise addition of a stabilised enolate followed by trapping of the initially formed S-ylid 2 with an aldehyde to provide vinyl epoxides 3 in a two-step, three-component process.
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