Electrochemical oxidation of 1-trimethylsilyl-1,3-dienes
1987; Elsevier BV; Volume: 28; Issue: 2 Linguagem: Inglês
10.1016/s0040-4039(00)95688-0
ISSN1873-3581
AutoresJun‐ichi Yoshida, Toshiki Murata, Sachihiko Isoe,
Tópico(s)Asymmetric Synthesis and Catalysis
ResumoElectrochemical oxidation of 1-trimethylsilyl-1,3-dienes in methanol afforded 1,1,4-trimethoxy-2-butene derivatives, which were readily hydrolyzed to the corresponding α,β-unsaturated aldehydes. By combination of this electrochemical reaction with the synthesis of 1-trimethylsilyl-1,3-dienes from carbonyl compounds, 1,3-bis(trimethylsilyl)propene provides a β-formylvinyl anion equivalent.
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