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Artigo Revisado por pares
BIBTEX RIS

Facile and Regioselective Dealkylation of Alkyl Aryl Ethers Using Niobium( V ) Pentachloride

2005; Wiley; Volume: 2006; Issue: 3 Linguagem: Inglês

10.1002/ejoc.200500502

ISSN

1434-193X

Autores

Yukinori Sudo, Shigeru Arai, Atsushi Nishida,

Tópico(s)

Chemical Synthesis and Reactions

Resumo

Abstract A simple and facile method for the cleavage of carbon–oxygen bonds promoted by niobium pentachloride( V ) is described. Excellent yields and regioselectivities were observed with various alkyl aryl ethers to give the phenols. NMR studies revealed the formation of monoaryloxy niobium salt( V ), and a neighboring‐group effect may play a significant role in the regioselectivity. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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