Metallbindungsphänomene: Alkoholat‐Aggregate als unmittelbare Teilnehmer an Eliminierungsreaktionen
1973; Wiley; Volume: 56; Issue: 5 Linguagem: Inglês
10.1002/hlca.19730560519
ISSN1522-2675
AutoresManfred Schlosser, Gérald Jan, Edeline Byrne, J. Sicher,
Tópico(s)Chemical Reaction Mechanisms
ResumoAbstract In solvents of low polarity it is neither a monomolecular nor a dissociated alcoholal species which effects dehydrohalogenation of vic ‐dihaloalkanes and vic ‐dihalocycloalkanes but rather a dimeric, trimeric or tetrameric alcoholate aggregate. This behavior has important implications for the stereochemical outcome of such elimination reactions.
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