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Reply to comment by R. Francois et al. on “Do geochemical estimates of sediment focusing pass the sediment test in the equatorial Pacific?”: Further explorations of 230 Th normalization

2007; American Geophysical Union; Volume: 22; Issue: 1 Linguagem: Inglês

10.1029/2006pa001373

ISSN

1944-9186

Autores

Mitchell W Lyle, Nicklas G Pisias, Adina Paytan, José I. Martínez, Alan C Mix,

Tópico(s)

Geological formations and processes

Resumo

PaleoceanographyVolume 22, Issue 1 Regular ArticlesFree Access Reply to comment by R. Francois et al. on "Do geochemical estimates of sediment focusing pass the sediment test in the equatorial Pacific?": Further explorations of 230Th normalization Mitchell Lyle, Mitchell Lyle [email protected] Department of Oceanography, Texas A & M University, College Station, Texas, USASearch for more papers by this authorNicklas Pisias, Nicklas Pisias College of Ocean and Atmospheric Sciences, Oregon State University, Corvallis, Oregon, USASearch for more papers by this authorAdina Paytan, Adina Paytan Department of Geological and Environmental Sciences, Stanford University, Stanford, California, USASearch for more papers by this authorJose Ignacio Martinez, Jose Ignacio Martinez Departmento de Geologia, Universidad Escuela de Administración, Finanzas y Tecnología, Medellin, ColombiaSearch for more papers by this authorAlan Mix, Alan Mix Department of Geological and Environmental Sciences, Stanford University, Stanford, California, USASearch for more papers by this author Mitchell Lyle, Mitchell Lyle [email protected] Department of Oceanography, Texas A & M University, College Station, Texas, USASearch for more papers by this authorNicklas Pisias, Nicklas Pisias College of Ocean and Atmospheric Sciences, Oregon State University, Corvallis, Oregon, USASearch for more papers by this authorAdina Paytan, Adina Paytan Department of Geological and Environmental Sciences, Stanford University, Stanford, California, USASearch for more papers by this authorJose Ignacio Martinez, Jose Ignacio Martinez Departmento de Geologia, Universidad Escuela de Administración, Finanzas y Tecnología, Medellin, ColombiaSearch for more papers by this authorAlan Mix, Alan Mix Department of Geological and Environmental Sciences, Stanford University, Stanford, California, USASearch for more papers by this author First published: 06 March 2007 https://doi.org/10.1029/2006PA001373Citations: 27 This is a commentary on DOI: AboutSectionsPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL 1. Introduction [1] The 230Th method of Francois et al. [2004] to determine sediment focusing and to normalize sediment fluxes depends on the following two primary assumptions: (1) the abundance of 230Th remains a constant within the sediment rain, i.e., the mass ratio of 230Th to bulk sediment is the same in a horizontally transported mixture as in the particulate material falling from the surface, and (2) a sufficient source of sediments exists to supply both the sediment and the excess 230Th. We show, via a mass balance of the Panama Basin, that 230Th:sediment ratios of particulate rain vary by well over an order of magnitude, and that the shallow regions around the Panama Basin are too small to supply the 230Th model fluxes. We reiterate the conclusion of Lyle et al. [2005] that there must be significant advection of 230Th in the oceans without movement of large amounts of bulk sediment. Francois et al. [2007] have been unable to identify any independent means to test whether the 230Th-based sediment focusing estimates are correct, and cannot explain why their model results do not agree with geophysical observations or other sediment measurements in cores. We stress that neither sediment focusing nor sediment fluxes can be modeled by 230Th measurements alone. [2] Lyle et al. [2005] present several lines of evidence to search for sediment focusing, which included subbottom profiling, seismic reflection, data from sediment cores, geographic distribution of sedimentary events, current patterns, and sediment dynamics. All of these lines of evidence imply that large-scale horizontal transport of sediment (on the order of 50% of the vertical flux) can indeed occur over length scales of tens of kilometers. However, massive sediment focusing of 100% to 700% of particle rain, over length scales of hundreds of kilometers, as suggested by Francois et al. [2004], are only achievable under very special (and not common) circumstances. Such extreme levels of sediment focusing should leave evidence easily detectable by marine geological methods and are independently testable. [3] Lyle et al. [2005] is not the first study to suggest that 230Th systematics is more complex than presented by Francois et al. [2004]. Walter et al. [2000], note that 230Th inventories in the slowly accumulating sediments of the Weddell Sea basin ( 200 times more efficiently by the lithogenic fine fraction than by biogenic fractions of sediments in the equatorial Pacific [Luo and Ku, 2004a, 2004b] and such scavenging may be prevalent in the water column. Chase et al. [2002] and Chase and Anderson [2004] challenged this conclusion about the lithogenic distribution coefficient, but still suggest that the apparently high distribution coefficient for lithogenic particles results from the association of 230Th and the fine sediment fraction, not just the lithogenic particles. [5] Finally, a wide spectrum of studies continues to find that slowly accumulating sediments in deep basins throughout the world's oceans consistently have smaller inventories of 230Th than expected from seawater production, a fraction of which apparently is exported up and out of these basins [Dymond and Veeh, 1975; Huh et al., 1997; Moran et al., 2005]. The deep basins of the ocean should behave as sinks, not sources for 230Th if 230Th leaves the cycle as soon as it joins the sediment column. More studies of 230Th from the deep gyre basins need to be made to understand the dynamics of 230Th in slowly accumulating sediments (<0.5 cm/kyr). 2. A Mass Balance of the Panama Basin [6] Here we explore whether the assertion made by Francois et al. [2004] that the 230Th normalization method can indeed correct burial fluxes (sediment mass accumulation rates or MAR) in the Panama Basin in the absence of other information about the sedimentary environment. We reiterate that selective transport of the sediment fine fraction by horizontal advection contradicts their fundamental assumption: that the 230Th ratio to bulk sediment rain at any given site is constant and depends only on seawater U concentration and water depth. We also show that, near continental margins, the large differences in water depth and bulk sediment fluxes to different parts of the margin naturally set variable 230Th:bulk sediment ratios and make the correction based upon data from a single core impracticable. We also reiterate that 230Th should be treated as an important tool in studies to understand sediment redistribution, but that it is not the whole toolbox and should be used in the context of specific geological and sedimentological conditions. [7] Figure 1 shows a map and a first-order model of the Panama Basin, divided up into sedimentary regimes, to help clarify our arguments. In the model we have divided up the basin and its surrounding boundaries into four types of basic sedimentary regimes: (1) continental shelf and upper slope with an average depth of 500 m; (2) shallow pelagic tops of aseismic ridges at an average depth of 1500 m; (3) deep aseismic ridges with an average depth of 2000 m; and (4) the deep pelagic basin with an average depth of 3000 m. We use this model to explore quantitatively the production and movement of 230Th and sediment within the Panama Basin. Note that the 230Th flux can be discussed independently of total sediment flux. Figure 1Open in figure viewerPowerPoint (left) Block model of the Panama Basin to estimate the 230Th inventory for the deep basin and for the ridges and margins surrounding it. The inventory is reported in Table 1. (right) Map of Panama Basin from Lyle et al. [2005] showing bathymetry and location of cores that have a depositional event at the last glacial maximum. [8] The model maximizes the potential size of the source regions and the potential 230Th available for horizontal transport into the basin. Specifically, we deliberately skewed the depth of the ridges and margins to the deep end of their bathymetric range in order to maximize the 230Th flux that might be horizontally transported (e.g., we allow for the maximum possible excess 230Th to be available for redistribution). Using the assumption that U is uniformly distributed in the water column, the vertical flux of 230Th to the seafloor is dependent only on the U concentration and water depth [Francois et al., 2004]. The 230Th inventory is a product of the vertical flux by the area for each regime (Table 1). Table 1. The 230Th Inventory for Panama Basin Based on Figure 1 Area, m2 × 109 Water Depth, m Volume of Water for 230Th Production, m3 × 1012 Total 230Th Inventory, dpm × 1012 Shallow blocks Middle America shelf 136 500 68 1.8 South America Shelf 145 500 73 1.9 Cocos Ridge 222 2000 444 11.8 Malpelo Ridge 48 2000 96 2.6 E. Carnegie Ridge 38 1500 57 1.5 Carnegie Ridge 151 2000 302 8.1 Galapagos Platform 30 1500 45 1.2 Shallow total 770 28.9 Deep Panama Basin 610 3000 1830 48.9 [9] Because the 230Th inventory is dependent upon water depth, shallow areas like the Middle America shelf and the South American shelf make relatively small contributions to the total 230Th inventory of the Panama Basin, although they have a large impact on the sediment budget. These two shelves have a combined area equal to 46% of the deep Panama Basin yet the combined 230Th inventory of the two shelves is less than 8% of the deep basin inventory. The total 230Th inventory of the shallow rim of the Panama Basin (plus the Malpelo Ridge in the center) is less than 60% of that of the Panama Basin floor (Table 1) even though the total shallow area is more than 25% greater than the basin floor. [10] For 230Th flux corrections to work, the 230Th activity must be constant, as Francois et al. [2004] pointed out. Imagine, for example, that pure 230Th particles are advected to a point where all the vertical sediment flux is preserved and buried in the sediment column. The focusing factor will then be greater than 1, because the 230Th burial will be greater than the water column production. The normalization will overcorrect for the horizontally advected sediment because 230Th is being added without any additional sediment. The same situation will occur at any time the 230Th activity of the horizontally advected sediment is substantially higher than that of the vertical particulate rain. The converse is also true: Horizontally advected sediments with lower 230Th activity than that of the vertical particulate rain will produce an undercorrection of the focused flux. [11] Ocean margins are areas of high-particulate rain but low 230Th inventory. Erosion from the shelves should contribute large amounts of sediment but low amounts of 230Th, i.e., a low 230Th:bulk sediment ratio. In contrast, erosion and redistribution within the deep basin will have a much higher 230Th:bulk sediment ratio. For example, if particulate rain to the shelf zones is 5 times higher than the vertical component of particulate rain to the pelagic basins, then the 230Th:bulk sediment of the shelf environment is 30 times smaller than that of the pelagic basin. The difference in water depth between the basin and the shelf causes the water column production of 230Th to be 6 times higher in the basin than over the shelf. Thus horizontal movement of 230Th derived from basin sediments will mark a movement of 30 times less sediment than the same amount of 230Th derived from the shelf. One needs to know the various sources of sediment that accumulate at any given site, their relative contribution to the total sediment and their original 230Th:bulk sediment ratio in order to convolute the original sediment rain rate from the 230Th signature. [12] The use of 230Th is further complicated when sediments fractionate by size: During horizontal transport the fine sediment fraction always travels farther than the coarser fractions. 230Th continuously adsorbs onto particles as they move through the water column and surface sediment. It preferentially adsorbs on the fine fraction because adsorption is correlated to surface area and the fine fraction has significantly higher surface area than coarser fractions. Any separation of fine fraction from coarse fraction along the transport route moves high amounts of 230Th, but low bulk mass of total sediment. Removal of fines is often seen on ridge tops, and is a feature of the ridges around the Panama Basin [Moore et al., 1973]. Size fractionation and transport of the fines can raise the 230Th:bulk sediment ratio by large amounts and causes a huge overestimate of horizontal sediment flux at the site of deposition. The 230Th normalization can thus either overestimate or underestimate the mass of sediment transported horizontally: It should not be used as a quantitative tool without other data to determine the source and transport process of the sediment. [13] Lyle et al. [2005] explored two separate cases where the focusing factor was at least double the vertical particulate rain. The excess sediment is assumed to come through horizontal redistribution of the sediments from elsewhere. In the first case Holocene and late Pleistocene sediments under the Pacific equator from 86° W to 161°E [Higgins et al., 1999; Marcantonio et al., 2001; Loubere et al., 2004] all typically have a focusing factor near 2, meaning that the model predicts that half the sediment was derived from elsewhere. However, in no case has a source region been identified for the excess sediment, nor is there even a plausible delivery method. In the Panama Basin, where the high surrounding ridges provide a possible source region, the few published data also reveal a focusing factor of 2. [14] There is also a mass accumulation rate (MAR) event at the last glacial maximum in the eastern Pacific including most of the Panama Basin. The 18 ka MAR event has been attributed to high productivity [Pedersen, 1983; Lyle et al., 1988; Pedersen et al., 1991; Lyle et al., 2002]. and is found throughout much of the Panama Basin, on top of the Carnegie Ridge, and in the northern Peru Basin [Lyle et al., 2005]. Loubere et al. [2004] and Francois et al. [2004] contend through 230Th normalization that the vertical rain of sediment did not change during the 18 ka MAR event. Instead they propose that sediment focusing increased from 2 to a factor of 8. In other words Loubere et al. [2004] and Francois et al. [2004] contend that there was no productivity event at 18 ka but instead a major sediment transport event. [15] Lyle et al. [2005] determined that local redistribution on a scale of tens of kilometers has caused depositional variation in the range of 30 to 50% of the total sediment flux within the abyssal hill topography of the western Panama Basin. This is the case equivalent to what Francois et al. [2004] referred to as bottom nepheloid transport. We also noted that adjacent depositional areas maintained that level of difference in burial for over 2 million years, even during the 18 ka MAR event. Time series of MAR at different spots in the basin, when normalized for different average MAR, have coherent changes in deposition. [16] These observations imply that there is a small-scale (∼10 km scale) syndepositional focusing that affects the average rate of burial but not the time series (the changes in MAR through time). Proposed high focusing events, like the 18 ka MAR event, must be derived from outside the local near-bottom region to leave the coherent MAR time series. The additional sediment must appear either through a change in vertical particle flux (e.g., export production) or by high transport from a distal sediment source. The only likely source for horizontally advected sediment to the deep Panama Basin is the high topography surrounding it. [17] Moore et al. [1973] have shown that the ridges surrounding Panama Basin provide additional sediment to the basin and that much of the horizontally advected sediment may derive from water inflow into the Panama Basin across a low saddle in the Carnegie Ridge (see Figure 1). Tsuchiya and Talley [1998] have shown that the density, salinity, and temperature of western Panama Basin deep waters are consistent with flow into the region from the south over the Carnegie Ridge. Lonsdale and Malfait [1974] observed sand waves in the saddle of the Carnegie Ridge at a depth of 2650 m, about the same depth as core Y69-71 featured by Lyle et al. [2005], Francois et al. [2004], and Loubere et al. [2004]. Y69-71 is located over 100 km to the northwest of the Carnegie Ridge saddle, however (Figure 1). The Carnegie Ridge is clearly a viable source for horizontally advected sediment. However, can it supply enough sediment or 230Th to match the model-based sediment focusing? It is important to explore this question because the 18 ka MAR event is also found on the shallowest part of the Carnegie Ridge (V19-27 [Lyle et al., 2002]), even though average MAR on the top of the ridge is about half that in nearby basin cores. [18] Moore et al. [1973] estimated via a simple model of carbonate accumulation and dissolution that about 14% of Panama Basin sediments were derived from the surrounding ridges. This number is probably an overestimate because they used a very high abundance of carbonate in the model particulate rain (95%) versus an observed value of 65% in the only nearby sediment trap [Cobler and Dymond, 1980]. Nevertheless, there is evidence for a source of fine sediment (the ridge top sediments are significantly coarser than the basin sediments) that could be horizontally advected into the western Panama Basin. [19] Let us now explore the inventory of 230Th in the Holocene and the implications for the last glacial maximum. Y69-71 (Figure 1) is located in the western Panama Basin, between the Carnegie Ridge and the active Galapagos spreading center. If the sediment source area is the Carnegie Ridge, and the additional sediment is derived via strong currents through the saddle, the minimum size of the depositional area is from the beginning of the Panama Basin just to the north of the saddle in the Carnegie Ridge to the Galapagos Spreading center, and westward to just past the position of Y69-71. We use this as a minimum because bottom current velocities should drop quickly after passing through the confined passage. We use a minimum depositional area to make the possible influence of horizontal sediment movements as large as possible. This depositional region, shown as "sink region" on Figure 1, has an area of 46 × 109 m2, and has a vertical 230Th inventory of 3.2 × 1012 dpm, using an average water depth of 2500 m. [20] As Table 1 shows, there is sufficient area on the Carnegie Ridge to provide the excess 230Th inventory to the sink region in the Holocene. The 230Th inventory of the Carnegie Ridge is 2.5 times as large as the sink zone so the Carnegie ridge can produce a focusing factor of ∼3.5, if the entire 230Th inventory is stripped from the Carnegie Ridge and delivered to the sink zone. However, one result of this scenario is that the Carnegie Ridge could not supply large amounts of 230Th or sediment to the rest of the Panama Basin. [21] Because deep water moves into the Panama Basin from the south and must be exported over the ridge tops, any water and any horizontally advected sediment on Cocos Ridge, the northern boundary of the Panama Basin, moves out and away from the Panama Basin. The Cocos Ridge should thus supply minimal amounts of horizontally advected sediment to the deep Panama Basin. [22] If the Carnegie Ridge is supplying sediment to the sink area to achieve a focusing factor of 2, the rest of the basin receives sediment and 230Th from the Carnegie Ridge to achieve a maximum focusing factor of about 1.1, assuming all sediment is removed from the Carnegie Ridge (which it is not). Therefore we suggest that the best place to look for sediment focusing around Y69-71 is to examine sediments elsewhere in the Panama Basin and do the mass balance. [23] At the LGM there is a major mass balance problem, because a focusing factor of 8 was measured in the sink region, for an added 230Th inventory of 22.4 × 1012 dpm from sources other than the vertical particulate rain. This is equivalent to 276% of the 230Th inventory to the Carnegie Ridge, or 78% of the entire 230Th inventory of all the ridges and shallow sediment regimes surrounding the Panama Basin. According to the model presented by Francois et al. [2004], the production of 230Th is a constant and independent of the sediment flux, so roughly 80% of the total 230Th inventory from the ridges must somehow concentrate itself on 8% of the Panama Basin floor. [24] Alternately the minimum depositional area could have gotten significantly smaller, so that the horizontal sediment focusing could have become significantly more focused at the last glacial maximum. If all the 230Th inventory of the Carnegie Ridge were moved to the sink zone, the sink zone at the last glacial maximum must still have shrunk to one third of its Holocene size. So, at a putative time of maximum horizontal advection, the 230Th model requires that the depositional area must shrink. The large focusing factor at 18 ka also requires that the rest of the Panama basin should experience drops in focusing factor at the LGM, another easy test that has yet to be conducted. 3. Conclusions [25] We finish by coming back to our points: There can be significant horizontal movements of sediment in the pelagic regime as has been recognized long ago by marine geologists. However, horizontal sediment focusing cannot be assessed by 230Th-based models alone. Independent information is needed about source characteristics, including size of the source region, its sediment composition, and its degree of winnowing. Francois et al. [2007] objected to the alternate mechanisms we presented to reconcile the higher than expected levels of 230Th found in some sediments with the lack of independent evidence for high levels of sediment movement. They have yet to provide alternative hypotheses of their own. We have shown here that the 230Th inventories around the Panama Basin do not balance with the focusing factors calculated by 230Th. As we said [Lyle et al., 2005], the discrepancy could be resolved if significant 230Th travels laterally without high fluxes of sediment, or if other yet undetermined mechanisms exist to decouple bulk sediments and 230Th. We need to better understand these processes that lead to 230Th advection and accumulation if we are to make better use of 230Th as a tracer of horizontal sediment flux. Acknowledgments [26] The research for this reply was supported by NSF grants OCE-0240906 and OCE-0451291 to M. W. Lyle. Supporting Information Filename Description palo1370-sup-0001-t01.txtplain text document, 503 B Tab-delimited Table 1. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References Chase, Z., and R. F. 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(2007), Comment on "Do geochemical estimates of sediment focusing pass the sediment test in the equatorial Pacific?" by Lyle et al. Paleoceanography, 22, PA1216, doi:10.1029/2005PA001235. Higgins, S., et al. (1999), Enhanced sedimentation along the equator in the western Pacific, Geophys. Res. Lett., 26, 3489– 3492. Huh, C.-A., et al. (1997), Natural radionuclides and plutonium in sediments from the western Arctic Ocean: Sedimentation rates and pathways of radionuclides, Deep Sea Res., Part II, 44, 1725– 1743. Lonsdale, P., and B. Malfait (1974), Abyssal dunes of foraminiferal sand on the Carnegie Ridge, Geol. Soc. Am. Bull., 85, 1697– 1712. Loubere, P., F. Mekik, R. Francois, and S. Pichat (2004), Export fluxes of calcite in the eastern equatorial Pacific from the Last Glacial Maximum to the present, Paleoceanography, 19, PA2018, doi:10.1029/2003PA000986. Luo, S., and T.-L. 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Roy-Barman, M., et al. (2005), The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment), Earth Planet. Sci. Lett., 240, 681– 693. Tsuchiya, M., and L. D. Talley (1998), A Pacific hydrographic section at 88°W: Water-property distribution, J. Geophys. Res., 103, 12,899– 12,918. Walter, H. J., et al. (2000), Reduced scavenging of 230Th in the Weddell Sea: Implications for paleoceanographic reconstructions in the South Atlantic, Deep Sea Res., Part I, 47, 1369– 1387. Citing Literature Volume22, Issue1March 2007 FiguresReferencesRelatedInformation

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