Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN)6]2: The relative importance of accessible coordination sites and van der Waals interactions

Artigo Revisado por pares

Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN)6]2: The relative importance of accessible coordination sites and van der Waals interactions

2006; Royal Society of Chemistry; Issue: 38 Linguagem: Inglês

10.1039/b607250j

ISSN

1364-548X

Autores

Karena W. Chapman, Peter J. Chupas, Evan Maxey, James W. Richardson,

Tópico(s)

Magnetism in coordination complexes

Resumo

Selective recovery of the guest-framework interactions for H(2) adsorbed in a nanoporous Prussian Blue analogue, through differential X-ray and neutron pair distribution function analysis at ca. 77 K, suggests that the H(2) molecule is disordered about a single position at the centre of the pore, ((1/4),(1/4),(1/4)), without binding at accessible Mn(II) sites.

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Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN)6]2: The relative importance of accessible coordination sites and van der Waals interactions