Hexa‐ tert ‐butyldisilane–the Molecule with the Longest SiSi Bond
1986; Wiley; Volume: 25; Issue: 1 Linguagem: Inglês
10.1002/anie.198600791
ISSN1521-3773
AutoresNils Wibeŕg, Harald Schuster, Arndt Simon, Karl Peters,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoSteric repulsion of the tert ‐butyl groups in the disilane 2 results in a Si‐Si distance about 35 pm greater than that usually found in disilanes. 2 is formed via a radical intermediate upon reaction of nitrosyl cations with 1 , MNa, K. equation image
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