Gif-type oxidation systems. Evidence for a second intermediate between saturated hydrocarbon and ketone
1990; Elsevier BV; Volume: 31; Issue: 20 Linguagem: Inglês
10.1016/0040-4039(90)80156-g
ISSN1873-3581
AutoresDerek H. R. Barton, Éva Csuhai, Nubar Ozbalik,
Tópico(s)Oxidative Organic Chemistry Reactions
ResumoThe addition of dianisyl telluride to a GifIV oxidation of adamantane has a marked effect on the ratio of ketone to secondary alcohol formed. This is interpreted as an indication of a second intermediate in the conversion of saturated hydrocarbons into ketones. This second intermediate is probably an FeIII alkoxide.
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