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Total synthesis of the alkaloid (±)-deoxyaspidodispermine

1974; Royal Society of Chemistry; Issue: 8 Linguagem: Inglês

10.1039/c39740000296

2050-5639

Takeshi Ohnuma, Koh‐ichi Seki, Takeshi Oishi, Yoshio Ban,

Synthetic Organic Chemistry Methods

(±)-Deoxyaspidodispermine, whose (–)-form was isolated from Aspidosperma dispermum and demonstrated as formula (VIIa) of a unique constitution among Aspidosperma alkaloids, was first synthesized under stereocontrol to directly prove the correctness of the proposed structure by chemical means.