Portal de Periódicos da CAPES

Synthesis and hydrolysis of gas-phase lanthanide and actinide oxide nitrate complexes: a correspondence to trivalent metal ion redox potentials and ionization energies

2015; Royal Society of Chemistry; Volume: 17; Issue: 15 Linguagem: Inglês

10.1039/c5cp00515a

1463-9084

Ana F. Lucena, Célia Lourenço, Maria C. Michelini, Philip X. Rutkowski, José M. Carretas, Nicole Zorz, Laurence Berthon, Ana Dias, M. Conceição Oliveira, John K. Gibson, Joaquim Marçalo,

Catalytic Processes in Materials Science

Gas-phase hydrolysis of lanthanide/actinide MO 3 (NO 3 ) 3 − ions relates to the stabilities of the M IV oxidation states, which correlate with IV/III solution reduction potentials and 4th ionization energies.