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BIBTEX RIS

Transition metal chemistry V. Calculation of CO stretching force constants of cis disubstituted group VI metal carbonyls and (organo) group IV metal iron carbonyl complexes with lolca C2v symmetry

1970; Elsevier BV; Volume: 25; Issue: 1 Linguagem: Inglês

10.1016/s0022-328x(00)86222-1

ISSN

1872-8561

Autores

F.T. Delbeke, Erik Claeys, G.P. Van Der Kelen, Z. Eeckhaut,

Tópico(s)

Thermal and Kinetic Analysis

Resumo

Using the Cotton and Kraihanzel force field, a more exact direct method is applied for calculating the CO stretching force constants of substituted metal carbonyls of general formula cis-L2M(CO)4 (M = Mo, W, Cr; L = phosphine or amine) and of complexes of formula [R2MFe(CO)4]2(M = Si, Ge, Sn or Pb),(R3Sn)2Fe(CO)4, R4M3[Fe(CO)4]4 (M = Sn or Pb) and M[Fe(CO)4]4 (M = Ge, Sn or Pb).

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