Synthesis of cis-(1→3)-glycosides of allyl 2-acetamido-4,6-O-benzylidene-2-deoxy-α-d-glucopyranoside
2004; Elsevier BV; Volume: 339; Issue: 7 Linguagem: Inglês
10.1016/j.carres.2004.01.014
ISSN1873-426X
AutoresJanusz Madaj, Magdalena Jankowska‐Wajda, Andrzej Wiśniewski,
Tópico(s)Natural product bioactivities and synthesis
ResumoSyntheses of allyl 2,3,4-tri-O-benzyl-α-d-gluco- and d-galactopyranosyluronate-(1 → 3)-2-acetamido-4,6-O-benzylidene-2-deoxy-α-d-glucopyranoside via oxidation of the hydroxymethyl group of allyl 2,3,4-tri-O-benzyl-α-d-gluco- and d-galactopyranosyl-(1 → 3)-2-acetamido-4,6-O-benzylidene-2-deoxy-α-d-glucopyranoside under Jones conditions are described. Structures of the title compounds were confirmed by 1H and 13C NMR spectroscopy.
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