The First Isolation and Structural Characterization of a Lanthanoid−Imine Azametallacyclopropane Complex, [Yb(η 2 -Ph 2 CNPh)(hmpa) 3 ]
1996; American Chemical Society; Volume: 15; Issue: 26 Linguagem: Inglês
10.1021/om960900h
ISSN1520-6041
AutoresYoshikazu Makioka, Yuki Taniguchi, Yuzo Fujiwara, Ken Takaki, Zhaomin Hou, Yasuo Wakatsuki,
Tópico(s)Synthesis and characterization of novel inorganic/organometallic compounds
ResumoA dianionic lanthanoid(II)−imine azametallacyclopropane complex, [Yb(η2-Ph2CNPh)(hmpa)3] (hmpa = hexamethylphosphoramide), has been directly synthesized by the reaction of ytterbium metal with N-(diphenylmethylidene)aniline in THF/HMPA and structurally characterized by X-ray analysis.
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