Interactions of tetra-μ-acetato dirhodium(II) with sulfur-containing aminoacids
1980; Elsevier BV; Volume: 46; Linguagem: Inglês
10.1016/s0020-1693(00)84175-4
ISSN1873-3255
AutoresG. Pneumatikakis, P. Psaroulis,
Tópico(s)Magnetism in coordination complexes
ResumoThe reactions of aminoacids containing both free or acylated sulfydryl groups with the antitumour complex [Rh2(O2CMe)4] have been studied. The reactions of this complex with the first class of ligands lead to monomeric square planar rhodium(II) (S,N) bonded chelate complexes, which have been characterized by elemental analyses, ir, electronic and esr spectra, and by room temperature magnetic susceptibility measurements. The reactions with the second class of ligands lead to the formation of 1:2 adducts without breaking of the acetato cage and the adducts were characterized by the same techniques.
Referência(s)