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Rigorous derivation of entropy balance for electrochemical systems

1986; Elsevier BV; Volume: 31; Issue: 5 Linguagem: Inglês

10.1016/0013-4686(86)85030-7

1873-3859

Rolf Haase,

Electrochemical Analysis and Applications

It is shown how the basic thermodynamic concepts for electrochemical systems have to be used to derive the equations for the entropy balance rigorously. Account is taken of the condition of zero space charge within conducting phases and of the open character of the system for non-zero electric current.