[CoII2L(NCS)2(SCN)2]: der erste Cobaltkomplex mit Austauschwechselwirkungs- und Spin-Crossover-Effekten
1999; Wiley; Volume: 111; Issue: 3 Linguagem: Alemão
10.1002/(sici)1521-3757(19990201)111
ISSN1521-3757
AutoresSally Brooker, Paul G. Plieger, Boujemaa Moubaraki, Keith S. Murray,
Tópico(s)Metal complexes synthesis and properties
ResumoAngewandte ChemieVolume 111, Issue 3 p. 424-426 Zuschrift [CoII2L(NCS)2(SCN)2]: der erste Cobaltkomplex mit Austauschwechselwirkungs- und Spin-Crossover-Effekten Sally Brooker, Sally Brooker [email protected] Department of Chemistry, University of Otago, PO Box 56, Dunedin (Neuseeland), Fax: (+64) 3-479-7906Search for more papers by this authorPaul G. Plieger, Paul G. Plieger Department of Chemistry, University of Otago, PO Box 56, Dunedin (Neuseeland), Fax: (+64) 3-479-7906Search for more papers by this authorBoujemaa Moubaraki, Boujemaa Moubaraki Department of Chemistry, Monash University, Clayton, Victoria 3168 (Australien), Fax: (+61) 3-990-545-97Search for more papers by this authorKeith S. Murray, Keith S. Murray [email protected] Department of Chemistry, Monash University, Clayton, Victoria 3168 (Australien), Fax: (+61) 3-990-545-97Search for more papers by this author Sally Brooker, Sally Brooker [email protected] Department of Chemistry, University of Otago, PO Box 56, Dunedin (Neuseeland), Fax: (+64) 3-479-7906Search for more papers by this authorPaul G. Plieger, Paul G. Plieger Department of Chemistry, University of Otago, PO Box 56, Dunedin (Neuseeland), Fax: (+64) 3-479-7906Search for more papers by this authorBoujemaa Moubaraki, Boujemaa Moubaraki Department of Chemistry, Monash University, Clayton, Victoria 3168 (Australien), Fax: (+61) 3-990-545-97Search for more papers by this authorKeith S. Murray, Keith S. Murray [email protected] Department of Chemistry, Monash University, Clayton, Victoria 3168 (Australien), Fax: (+61) 3-990-545-97Search for more papers by this author First published: February 1, 1999 https://doi.org/10.1002/(SICI)1521-3757(19990201)111:3 3.0.CO;2-YCitations: 16AboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract Ein Spin-Crossover (350K, μeff=3.15μB pro Co-Ion; 4.5K, μeff=0.70μB pro Co-Ion) und eine schwache antiferromagnetische Austauschwechselwirkung (2 J=−11.7cm−1) zwischen den oktaedrisch koordinierten, doppelt Pyridazin-verbrückten Cobalt(II)-Ionen sind die besonderen Merkmale des Komplexes [CoII2L(NCS)2(SCN)2] (gezeigt ist der Ligand L), der auch durch eine Röntgenstrukturanalyse charakterisiert wurde. References 1 Siehe z. B.: O. Kahn, C. J. Martinez, Science 1998, 279, 44; 10.1126/science.279.5347.44 CASWeb of Science®Google Scholar Struktur eines CuII-Triazol-Analogons: Y. Garcia, P. J. van Koningsbruggen, G. Oravic, P. Guionneau, D. Chasseau, G. I. Cascarano, J. Moscovici, K. Lambert, A. Michalowicz, O. Kahn, Inorg. Chem. 1997, 36, 6357. 10.1021/ic970895p CASWeb of Science®Google Scholar 2 Siehe z. B.: H. Toftlund in Magnetism: A Supramolecular Function (Hrsg.: O. 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