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Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations

2006; American Chemical Society; Volume: 128; Issue: 30 Linguagem: Inglês

10.1021/ja0634167

1943-2984

Polly L. Arnold, Dipti Patel, Alexander J. Blake, Claire Wilson, Jason B. Love,

Porphyrin and Phthalocyanine Chemistry

The linear uranyl dication [UO2]2+ can be bound in one of two coordination sites in the ditopic Pacman-shaped pyrrolic macrocyle H4L. Incorporation of Mn2+, Fe2+, or Co2+ cations in the second donor compartment affords the first uranyl complexes with a transition-metal-functionalized oxo group.