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Avaliação de agente de ligação aziridínico por meio de técnicas de análises química e instrumental

2009; Aerospace Technology and Science Department; Volume: 1; Issue: 1 Linguagem: Inglês

10.5028/jatm.2009.01015561

2175-9146

Darci Corter Pires, Aparecida M. Kawamoto, Jairo Sciamareli, Elizabeth da Costa Mattos, Milton Faria Diniz, Rita de Cássia Lazzarini Dutra, Koshun Iha,

Thermal and Kinetic Analysis

A new method using wet chemistry and instrumental analysis has been developed for evaluating the ring-opening of aziridine tris [1-(2 methyl) aziridinyl] phosphide oxide (MAPO) of the bonding agent used in composite propellant. A reduction was observed in the intensity absorption bands in 1400 and 1040 cmˉ ¹ , characteristic of aziridinic ring. It was also observed, in some cases, that when the number of open aziridinyl ring increases, the NH band in the range 3400-3300 cmˉ ¹ , that appears with ring-opening, is located in the region of lower wave numbers. The study of the synthesis of MAPO derivative indicated side reactions such as homopolymerization of rings and also, with secondary hydroxyl of the 12-hydroxy stearic acid and probable humidity existent in the original sample.