Portal de Periódicos da CAPES

Visible light photocatalytic water splitting for hydrogen production from N-TiO2 rice grain shaped electrospun nanostructures

2012; Elsevier BV; Volume: 37; Issue: 10 Linguagem: Inglês

10.1016/j.ijhydene.2011.12.015

1879-3487

Veluru Jagadeesh Babu, M. K. Kumar, A. Sreekumaran Nair, Tan Lee Kheng, Suleyman I. Allakhverdiev, Seeram Ramakrishna,

Copper-based nanomaterials and applications

We report on the visible light-driven hydrogen production from splitting of water molecules by nitrogen-doped TiO2 (N-TiO2) with a rice grain-like nanostructure morphology. The N-TiO2 nanostructures are prepared using sol-gel and electrospinning methods followed by post-annealing of the composite nanofibers. The nanostructures are characterized by microscopy and spectroscopy. First order rate constants for the visible light-assisted photocatalysis in the degradation of methylene blue (MB) dye are found to be 0.2 × 10−3 and 1.8 × 10−3 min−1 for TiO2 and N-TiO2 (5 wt% of nitrogen), respectively. The N-TiO2 utilized in water splitting experiments and evaluated hydrogen (H2) of 28 and 2 μmol/h for N-TiO2 and TiO2, respectively. The improvement may be attributed due to the N-doping and higher surface area as ∼70 m2/g.