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BIBTEX RIS

Intramolecular Reductive Nitrosylation: Reaction of Nitric Oxide and a Copper(II) Complex of a Cyclam Derivative with Pendant Luminescent Chromophores

2004; American Chemical Society; Volume: 126; Issue: 21 Linguagem: Inglês

10.1021/ja049444b

ISSN

1943-2984

Autores

Kiyoshi Tsuge, Frank DeRosa, Mark D. Lim, Peter C. Ford,

Tópico(s)

Electron Spin Resonance Studies

Resumo

The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)2+ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.

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