A novel route to N-substituted allylamines by the reaction of allylsilanes with (ethoxycarbonyl)nitrene
1993; Elsevier BV; Volume: 34; Issue: 25 Linguagem: Inglês
10.1016/s0040-4039(00)60626-3
ISSN1873-3581
AutoresStefania Fioravanti, M. Antonietta Loreto, Lucio Pellacani, Sergio Raimondi, Paolo A. Tardella,
Tópico(s)Chemical Synthesis and Reactions
ResumoThe reaction of mono- and disubstituted allylsilanes with (ethoxycarbonyl)nitrene allowed the preparation of the N-substituted allylamines 2a, 2b, 2e and 2d in yields up to 60%. The 2-ethoxyoxazolines 3a, 3b and 3c were isolated as minor products.
Referência(s)