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A novel metal–organic ternary topology constructed from triangular, square and tetrahedral molecular building blocks

2007; Royal Society of Chemistry; Issue: 48 Linguagem: Inglês

10.1039/b712905j

1364-548X

Gregory J. McManus, Zhenqiang Wang, Derek A. Beauchamp, Michael J. Zaworotko,

Supramolecular Self-Assembly in Materials

A novel metal-organic network [Cu(4)(5-NH(2)-1,3-bdc)(4)(pyridine)(2)(H(2)O)(2)](n), displaying an unprecedented topology has been constructed utilizing the different coordinating functional groups of 5-NH(2)-1,3-bdc to generate a ternary network based upon vertex-linked triangular, square and tetrahedral molecular building blocks (MBBs).