Application of an Efficient Nonconventional Heterogeneous Catalyst for Biodiesel Synthesis from Pongamia pinnata Oil
2010; American Chemical Society; Volume: 24; Issue: 5 Linguagem: Inglês
10.1021/ef901514a
ISSN1520-5029
AutoresYogesh Chandra Sharma, Bhaskar Singh, John Korstad,
Tópico(s)Heat transfer and supercritical fluids
ResumoRecycled chicken eggshells after calcination have been used as a nonconventional heterogeneous catalyst for biodiesel synthesis from karanja oil from the pongam tree (Pongamia pinnata). The catalyst was characterized on X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and differential thermal analysis/thermogravimetric analysis (DTA/TGA). The formation of the calcium oxide phase was confirmed at 900 °C after calcination. A high biodiesel yield of 95.0% and conversion of 97.4% was obtained at an 8:1 (alcohol/oil) molar ratio, 2.5 wt % catalyst, and 2.5 h reaction time at 65 ± 0.5 °C. The biodiesel conversion was determined by Fourier transform nuclear magnetic resonance (FTNMR) spectroscopy.
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