One-step Synthesis of Straight-chain Carbohydrates from Formaldehyde and Syngas
1986; Oxford University Press; Volume: 15; Issue: 10 Linguagem: Inglês
10.1246/cl.1986.1731
ISSN1348-0715
AutoresTamon Okano, Hideo Ito, Hisatoshi Konishi, Jitsuo Kiji,
Tópico(s)Carbon Dioxide Capture Technologies
ResumoAbstract Straight-chain carbohydrates such as trioses, tetroses, pentoses, and hexoses are readily obtained in good yields by a reaction of formaldehyde with syngas in the presence of RhCl(CO)(PPh3)2 and tertiary amine. A selective synthesis of trioses or tetroses is also described.
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