Palladium-catalyzed regioselective reactions of silyl-substituted allylic carbonates and vinyl epoxide
1988; Elsevier BV; Volume: 29; Issue: 3 Linguagem: Inglês
10.1016/s0040-4039(00)80091-x
ISSN1873-3581
AutoresJiro Tsuji, Masami Yuhara, M. Minato, Hisao Yamada, Fumie Sato, Yuichi Kobayashi,
Tópico(s)Ferrocene Chemistry and Applications
ResumoPalladium-catalyzed reaction of α-substituted γ-trimethylsilylated allylic carbonates with carbonucleophiles took place regioselectively at the α-carbon. Reaction of formic acid took place at γ-carbon to afford allylic silanes. Methyl acetoacetate attacked regioselectively at 2-carbon of 1,2-epoxy-4-trimethylsilyl-3-butene.
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